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Master Bond adhesives

Zircar Zirconia ZYBF-1 Zirconia Bulk Fiber Insulation
Categories: Ceramic; Machinable Ceramic; Oxide; Zirconium Oxide

Material Notes: Zirconia Bulk Fibers Type ZYBF are yttria stabilized zirconia fibers available in five different forms, all having useful properties up to 2200°C. These polycrystalline fibers can be vacuum formed into rigid shapes, placed into cavities as loose fill insulation, or added to ceramic bodies and coatings for reinforcement. They are differentiated by fiber length, surface area, crystallite size and porosity. However, they all share the same fiber diameter and calcined chemical composition. All five forms of ZYBF are made using the “Zircar Process” which replicates the gross physical structure of an organic precursor fiber with a ceramic. Typically these fibers are 6 to10 microns in diameter and have a serrated outside surface.

All of our Zirconia Bulk Fibers are phase stabilized with ~10% yttria (yttrium oxide - Y2O3) to maintain a stable tetragonal / cubic structure. The yttria, in a solid solution within the zirconia, stabilizes the tetragonal / cubic structure by preventing the monoclinic to tetragonal crystal transformation that occurs at 1170°C in pure un-stabilized or insufficiently stabilized zirconia. This undesirable transformation causes an 11% volume change in the crystal unit cell size that can cause micro-cracking and reduced physical strength in the bulk solid.

Yttria stabilized zirconia is an electrical semiconductor at elevated temperatures. This conductivity arises from the different valences of ionic Zr+4 and Y+3. Electricity is conducted at elevated temperatures (~700-800°C) as oxygen ions are induced to flow through the stabilized zirconia structure. This phenomenon forms the basis of zirconia oxygen sensors.

Features:

  • Available in Five Different Forms
  • Low Thermal Conductivity
  • Highly Refractory
  • Low Heat Storage
  • Extreme High Temperature Stability
  • Fibers Stabilized with ~10 wt% Yttria
  • Lightweight
  • Available “Off the Shelf”

Information provided by Zircar Zirconia.

Key Words: ZrO2, zirconium oxide
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Physical PropertiesMetricEnglishComments
Bulk Density 0.120 g/cc0.00434 lb/in³
Loss On Ignition 4.0 - 6.0 %
@Temperature 950 °C,
Time 1800 sec
4.0 - 6.0 %
@Temperature 1740 °F,
Time 0.500 hour
Specific Surface Area 75 m²/g75 m²/g
Pore Size 0.00490 microns0.000193 milMedian Pierce desorption mesopore, based on surface area
 0.00500 microns0.000197 milMedian Pierce adsorption mesopore, based on surface area
 0.00600 microns0.000236 milMedian Pierce desorption mesopore, based on pore volume
 0.00750 microns0.000295 milMedian Pierce adsorption mesopore, based on pore volume
 
Component Elements PropertiesMetricEnglishComments
Chlorine, Cl 1.5 - 2.0 %1.5 - 2.0 %
H2O, Water 2.0 - 3.0 %2.0 - 3.0 %
HfO2 1.0 - 2.0 %1.0 - 2.0 %
Y2O3 10 %10 %
ZrO2 88 - 89 %88 - 89 %
 
Descriptive Properties
Trace Impurities<1%

Some of the values displayed above may have been converted from their original units and/or rounded in order to display the information in a consistent format. Users requiring more precise data for scientific or engineering calculations can click on the property value to see the original value as well as raw conversions to equivalent units. We advise that you only use the original value or one of its raw conversions in your calculations to minimize rounding error. We also ask that you refer to MatWeb's terms of use regarding this information. Click here to view all the property values for this datasheet as they were originally entered into MatWeb.

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