Applications: Catalyst for coupling 1,3-dienes with activate methylene compounds. Rhodium source for various asymmetric hydrogenation systems and asymmetric hydrosilylation of ketones. Rhodium source for asymmetric reductive aldol reaction. Cis-hydroboration of terminal alkynes. Rhodium source for [5 + 2] additions. Highly enantioselective for [2+2+2] carbocyclization reactions. Enantioselective hydroboration of cyclopropenes. Synonyms: LS-188423; Bis(cycloocta-1,5-diene)mu,mu'-dichlorodirhodium(I); Bis(1,5-cyclooctadiene)dirhodium(I) dichloride; bis(1,5-cyclooctadiene)-di-rhodium(i)-dichloride; Bis(cycloocta-1,5-diene)dichlorodirhodium; Chloro(1,5-cyclooctadiene)rhodium (I) dimer; BC213309; chloro(1,5-cyclooctadiene)-rhodium(I) dimer; PDJQCHVMABBNQW-MIXQCLKLSA-L; 1,5-Cyclooctadiene-iridium(I) chloride dimer, Chloro(1,5-cyclooctadiene)iridium(I) dimer Smiles: C1CC=CCCC=C1.C1CC=CCCC=C1.[Cl-].[Cl-].[Rh].[Rh]; Information provided by Alfa Chemistry Materials. |