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Master Bond adhesives

LG Chemical NBR 3250 High Acrylonitrile Polymer
Categories: Polymer; Thermoset; Rubber or Thermoset Elastomer (TSE)

Material Notes: Description: NBR 3250 is a copolymer of butadiene and acrylonitrile manufactured by cold emulsion polymerization technology of Goodyear Tire and Rubber Company, USA. NBR 3250 is a non staining, medium mooney viscosity, and high acrylonitrile polymer designed to aid in processing operations such as calendaring and extruding for oil and fuel service products. NBR 3250 offers high resistance to fuels, solvents, oils and gas permeation. NBR 3250 is recommended to in industrial and automotive parts such as fuel hoses and packings. NBR 3250 is a low mooney version of NBR 3280.

CAS No: 9003-18-3

Information provided by LG Chemical

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Physical PropertiesMetricEnglishComments
Specific Gravity 0.990 g/cc0.990 g/cc
Volatiles 0.30 %0.30 %
Mooney Viscosity 55
@Temperature 100 °C
55
@Temperature 212 °F
ML 1+4
Ash <= 0.50 %<= 0.50 %
 
Mechanical PropertiesMetricEnglishComments
Hardness, Shore A  49
@Treatment Temp. 25.0 °C,
Time 252000 sec
49
@Treatment Temp. 77.0 °F,
Time 70.0 hour
Aged fuel C
 71
@Treatment Temp. 150 °C,
Time 1190 sec
71
@Treatment Temp. 302 °F,
Time 0.330 hour
Cured
 74
@Treatment Temp. 100 °C,
Time 252000 sec
74
@Treatment Temp. 212 °F,
Time 70.0 hour
Aged ASTM D #3 Oil
 75
@Treatment Temp. 100 °C,
Time 252000 sec
75
@Treatment Temp. 212 °F,
Time 70.0 hour
Aged ASTM D #1 Oil
 76
@Treatment Temp. 100 °C,
Time 252000 sec
76
@Treatment Temp. 212 °F,
Time 70.0 hour
Circulating Oven Aging
Tensile Strength at Break  13.9 MPa
@Treatment Temp. 25.0 °C,
Time 252000 sec
2020 psi
@Treatment Temp. 77.0 °F,
Time 70.0 hour
Aged fuel C
 17.7 MPa
@Treatment Temp. 150 °C,
Time 1190 sec
2570 psi
@Treatment Temp. 302 °F,
Time 0.330 hour
Cured
 18.1 MPa
@Treatment Temp. 100 °C,
Time 252000 sec
2630 psi
@Treatment Temp. 212 °F,
Time 70.0 hour
Aged ASTM D #3 Oil
 18.3 MPa
@Treatment Temp. 100 °C,
Time 252000 sec
2650 psi
@Treatment Temp. 212 °F,
Time 70.0 hour
Aged ASTM D #1 Oil
 18.5 MPa
@Treatment Temp. 100 °C,
Time 252000 sec
2680 psi
@Treatment Temp. 212 °F,
Time 70.0 hour
Circulating Oven Aging
 31.8 MPa
@Treatment Temp. 145 °C,
Time 2990 sec
4610 psi
@Treatment Temp. 293 °F,
Time 0.830 hour
cured; ASTM D412
Elongation at Break  370.2 %
@Treatment Temp. 25.0 °C,
Time 252000 sec
370.2 %
@Treatment Temp. 77.0 °F,
Time 70.0 hour
Aged fuel C
 377.5 %
@Treatment Temp. 100 °C,
Time 252000 sec
377.5 %
@Treatment Temp. 212 °F,
Time 70.0 hour
Aged ASTM D #1 Oil
 378.8 %
@Treatment Temp. 100 °C,
Time 252000 sec
378.8 %
@Treatment Temp. 212 °F,
Time 70.0 hour
Circulating Oven Aging
 379.5 %
@Treatment Temp. 100 °C,
Time 252000 sec
379.5 %
@Treatment Temp. 212 °F,
Time 70.0 hour
Aged ASTM D #3 Oil
 410 %
@Treatment Temp. 150 °C,
Time 1190 sec
410 %
@Treatment Temp. 302 °F,
Time 0.330 hour
Cured
 544 %
@Treatment Temp. 145 °C,
Time 2990 sec
544 %
@Treatment Temp. 293 °F,
Time 0.830 hour
cured; ASTM D412
300% Modulus 15.3 MPa
@Treatment Temp. 145 °C,
Time 2990 sec
2220 psi
@Treatment Temp. 293 °F,
Time 0.830 hour
cured; ASTM D412
Compression Set 20.4 %
@Temperature 100 °C,
Time 252000 sec
20.4 %
@Temperature 212 °F,
Time 70.0 hour
160°C x 30 min. Cured)
 
Descriptive Properties
Bound AN Content (%)41.5
ColorTan
ComponentsHAF (IRB#7)40 phr, ASTM D3187
 NBR 3250100 phr, ASTM D3187
 Stearic Acid1 phr, ASTM D3187
 Sulfur1.5 phr, ASTM D3187
 TBBS0.7 phr, ASTM D3187
 ZnO3 phr, ASTM D3187
Compound RecipeAntioxidant(3-C)1 phr
 Antioxidant(RD)2 phr
 Carbon Black(SRF)80 phr
 CZ2 phr
 NBR 3250100 phr
 Plasticizer(TP-95)10 phr
 Stearic Acid1 phr
 Sulfur0.5 phr
 TT1 phr
 Zinc Oxide5 phr
Rheometer0.8 mints1, 160°C x 12 min, 1° Arc, MDR
 2.5 lb-inML, 160°C x 12 min, 1° Arc, MDR
 2.5 mint'90, 160°C x 12 min, 1° Arc, MDR
 25.5 lb-inMH, 160°C x 12 min, 1° Arc, MDR
Volume Swell (%)-3.2Aged ASTM D #3 Oil (100°C x 70hrs)
 32.5Aged fuel C (23°C x 72hrs)
 -6.5Aged ASTM D #1 Oil (100°C x 70hrs)

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