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Master Bond adhesives

Nouryon Trigonox 21S Thermoset NAR tert-Butyl peroxy-2-ethylhexanoate
Categories: Other Engineering Material

Material Notes: Trigonox 21S is a peroxide formulation used for curing unsaturated polyester resin at elevated and high temperatures. Suitable as a kicker in formulations for pultrusion and SMC/BMC.

CAS number: 3006-82-4

EINECS/ELINCS No: 221-110-7

Applications: For polymer production: Polymerization of ethylene: Trigonox 21S is an efficient initiator for the production of Low Density Polyethylene (LDPE). It is used both for tubular and autoclave processes. In most cases a combination with other peroxides is used to ensure a broad reactivity range. Polymerization of styrene: in suspension polymerization processes, Trigonox 21S can be used for the polymerization of styrene at approximately 90°C. Trigonox 21 has an activity comparable with Dibenzoyl peroxide (Perkadox L-W75). Typically, Trigonox 21S is used in combination with initiators such as tert- Butyl peroxybenzoate (Trigonox C) and tert-Butylperoxy 2 ethylhexyl carbonate (Trigonox 117). For Thermoset: Trigonox 21S, tert-butyl peroxy 2 ethylhexanoate, is a perester which is used for the curing of unsaturated polyester resin at elevated and high temperatures. Trigonox 21S is preferred for the curing of UP resin based Hot Press Moulding formulation (such as SMC and BMC) in the temperature range of 120 - 160°C. As Trigonox 21S is a high reactive peroxide, it is very suitable as a kicker in formulations for pultrusion and SMC/BMC. In combination with a cobalt accelerator, Trigonox 21S is also applicable for the cure of UP resins in the temperature range of 60°C and higher. Application area can be air drying lacquers, diplacquers, wall panels, filament winding, etc.

Information provided by Nouryon

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Physical PropertiesMetricEnglishComments
Density 0.900 g/cc0.0325 lb/in³
Half-life  0.100
@Temperature 113 °C
0.100
@Temperature 235 °F
[hr]
 1.00
@Temperature 91.0 °C
1.00
@Temperature 196 °F
[hr]
 10.0
@Temperature 72.0 °C
10.0
@Temperature 162 °F
[hr]
Viscosity 4.3 cP4.3 cP
Molecular Weight 216.3 g/mol216.3 g/mol
Storage Temperature -30.0 - 10.0 °C-22.0 - 50.0 °F
 
Thermal PropertiesMetricEnglishComments
Decomposition Temperature 35.0 °C95.0 °FSelf-Accelerating Decomposition Temperature
 
Processing PropertiesMetricEnglishComments
Shelf Life 3.00 Month3.00 Month
 
Descriptive Properties
AppearanceClear liquid
Assay= 97.0 %
Color= 30 APHA
Content= 0.30 %Acid as 2-ethylhexanoic acid
 = 100 mg/kgInorganic + organic hydrolysable chloride
 = 1000 mg/kgTBHP
 = 7.18 %Active oxygen
Content (%)7.4Active oxygen content peroxide

Some of the values displayed above may have been converted from their original units and/or rounded in order to display the information in a consistent format. Users requiring more precise data for scientific or engineering calculations can click on the property value to see the original value as well as raw conversions to equivalent units. We advise that you only use the original value or one of its raw conversions in your calculations to minimize rounding error. We also ask that you refer to MatWeb's terms of use regarding this information. Click here to view all the property values for this datasheet as they were originally entered into MatWeb.

PNOURY1046 / 286569

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