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Ensinger PEI

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Silver Vanadium Oxide Fluoride, Ag4V2O6F2
Categories: Ceramic; Halide; Oxide

Material Notes: Silver Vanadium Oxide Fluoride, Ag4V2O6F2 (SVOF) is a being researched as a cathode for high capacity lithium batteries. It has a higher accessible silver content and a higher capacity than the commercial cathode material Silver Vanadium Oxide (SVO; Ag2V4O11). The SVOF cathode maintains a greater potential than SVO electrodes for extended periods of time, allowing optimal device performance essential for medical battery applications, such as implantable defibrillators. When used as a cathode in a lithium battery, SVOF has two distinct regions within the discharge curve - an upper plateau at 3.5 V attributed to silver reduction and a lower sloped region around 2.3 V attributed to the reduction of the vanadium oxide fluoride framework.

Key Words: SVOF, primary lithium battery cathode
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Physical PropertiesOriginal ValueComments
Density 6.03 g/ccCalculated
a Lattice Constant 5.594 Å
b Lattice Constant 10.548 Å
c Lattice Constant 12.459 Å
Beta Lattice Angle 90.314 °
Formula Units/Cell (Z) 4Unit Cell Volume = 735.3 ų
Molecular Weight 667.36 g/molFormula Weight
 
Electrical PropertiesOriginal ValueComments
Capacity (Battery) 251 mAh/g251 mAh/g nominal capacity; 148 mAh/g above 3 V.
 
Descriptive Properties
Space GroupP21/nMonoclinic, No. 14

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BSVOF / 322

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