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Elmet Technologies

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Celanese 51002164 Acetic Anhydride Kosher Grade
Categories: Fluid

Material Notes: CAS Number: 108-24-7

Product description: Acetic Anhydride is a clear, colorless liquid with a very pungent, penetrating, vinegar-like odor. It is completely miscible with diethyl ether and can be easily dissolved in the usual organic solvents; it reacts with alcohols. Acetic Anhydride is an excellent solvent for numerous organic and inorganic products. In the presence of water, Acetic Anhydride reacts slowly at room temperature to form acetic acid. At moderate and elevated temperatures, however, this reaction can be extremely exothermic and violent. It is accelerated by catalytic quantities of sulfuric acid or other mineral acids and may even be explosive.

Possible Applications: In the chemical industry, the reactivity of the acetyl group of Acetic Anhydride is used to synthesize end products and intermediates. Acetic Anhydride is widely employed industrially for its acetylating and dehydrating properties. A major use for it is the acetylation of cellulose to produce acetate fibers, plastics, coatings and films. It is especially valuable for the direct esterification of alcohols where acetic acid cannot be used. Another large use for Acetic Anhydride is in the manufacture of acetylsalicylic acid (aspirin), acetylcholine hydrochloride, acetophenacetin, sulfonamides, aceto-p-aminophenol, cortisone, acetanilide, theophylline, sulfa drugs, certain vitamins and hormones; and many other pharmaceuticals and pharmaceutical intermediates. Acetic Anhydride is also used to produce acetyl ricinoleates, triacetin, acetyl tributyl citrate, and other plasticizers. Triacetic glycerol esters are used as plasticizers in the plastics and paint industry, as fixatives in perfumery and as solvents for fungicides and basic dyes. Acetylated fatty acid monoglycerides and acetylated animal and vegetable fats are used as additives and auxiliaries in the food industry. In this connection, the relevant statutory food regulations must be observed. Another chemical use is in the manufacture of acetyl peroxide. Acetic Anhydride is also used as an intermediate in the manufacture of explosives, weed killers and in the chemical treatment of papers and textiles

Information provided by Celanese Corporation.

Key Words: Acetic Acid Anhydride, Ethanoic Anhydride
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Physical PropertiesOriginal ValueComments
Density 0.00427 g/ccVapor density
 1.0442 g/cc
@Temperature 50.0 °C
 1.0505 g/cc
@Temperature 45.0 °C
 1.0567 g/cc
@Temperature 40.0 °C
 1.0628 g/cc
@Temperature 35.0 °C
 1.069 g/cc
@Temperature 30.0 °C
 1.0751 g/cc
@Temperature 25.0 °C
 1.0811 g/cc
@Temperature 20.0 °C
 1.0872 g/cc
@Temperature 15.0 °C
 1.0932 g/cc
@Temperature 10.0 °C
 1.0991 g/cc
@Temperature 5.00 °C
 1.1051 g/cc
@Temperature 0.000 °C
Viscosity 0.62 cP
@Temperature 50.0 °C
 0.65 cP
@Temperature 45.0 °C
 0.70 cP
@Temperature 40.0 °C
 0.74 cP
@Temperature 35.0 °C
 0.79 cP
@Temperature 30.0 °C
 0.85 cP
@Temperature 25.0 °C
 0.91 cP
@Temperature 20.0 °C
 0.97 cP
@Temperature 15.0 °C
 1.05 cP
@Temperature 10.0 °C
 1.13 cP
@Temperature 5.00 °C
 1.23 cP
@Temperature 0.000 °C
Molecular Weight 102.09 g/mol
Vapor Pressure 0.000981 bar
@Temperature 0.000 °C
 0.00196 bar
@Temperature 5.00 °C
 0.00196 bar
@Temperature 10.0 °C
 0.00294 bar
@Temperature 15.0 °C
 0.00490 bar
@Temperature 20.0 °C
 0.00686 bar
@Temperature 25.0 °C
 0.00883 bar
@Temperature 30.0 °C
 0.0127 bar
@Temperature 35.0 °C
 0.0167 bar
@Temperature 40.0 °C
 0.0216 bar
@Temperature 45.0 °C
 0.0284 bar
@Temperature 50.0 °C
Surface Tension 28.3 dynes/cm
@Temperature 50.0 °C
 31.2 dynes/cm
@Temperature 30.0 °C
 32.7 dynes/cm
@Temperature 20.0 °C
 
Chemical PropertiesOriginal ValueComments
Critical Pressure 39.4 atm
Critical Temperature 332.8 °C
 
Electrical PropertiesOriginal ValueComments
Dielectric Constant 20.5
@Temperature 20.0 °C
 
Thermal PropertiesOriginal ValueComments
Heat of Vaporization 460 J/g
@Temperature 50.0 °C
 473 J/g
@Temperature 30.0 °C
 479 J/g
@Temperature 20.0 °C
CTE, linear 1200 µm/m-°C
Specific Heat Capacity 1.82 J/g-°C
@Temperature 20.0 °C
Liquid
 1.87 J/g-°C
@Temperature 30.0 °C
Liquid
 1.97 J/g-°C
@Temperature 50.0 °C
Liquid
Thermal Conductivity 0.158 W/m-K
@Temperature 50.0 °C
 0.163 W/m-K
@Temperature 30.0 °C
 0.165 W/m-K
@Temperature 20.0 °C
Melting Point >= -83.55 °C
Boiling Point 139.5 °C
@Pressure 0.101 MPa
Flash Point 49.0 °C
 
Descriptive Properties
Evaporation Rate0.46(n-Butyl Acetate =1)

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WCELAN918 / 177989

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