| Applications: A homogeneous hydrogenation catalyst which operates under mild conditions. Catalyst for the decarbonylation of aldehydes. Catalyst for regio- and stereoselective allylic substitution reactions. Alkyne hydro-phosphorylation Heck-type reaction with α,β-unsaturated esters. Alkyne arylation Allylic alcohol-olefin coupling. Terminal alkenes from ketones. Rh-catalyzed isomerization of α-aryl propargyl alcohols to indanones. Reductive deprotection of silyl groups. Synonyms: Wilkinson's catalyst Tris(triphenylphosphine)rhodium(I) chloride C54H45ClP3Rh 925.23 ca 250 degrees dec. 14694-95-2 "14,10047" 238-744-5 MFCD00010016 P273-P501a; Tris(triphenylphosphine)rhodium chloride; AS-12487; AN-15374; Tris(triphenylphosphine)rhodium monochloride; 16592-65-7; RhCl(PPh3)3, Rhodium(I) tris(triphenylphosphine) chloride, Wilkinson's catalyst, NSC 124140; chlorotris(triphenylphosphine)-rhodium(i); RTR-005847; tris(triphenylphosphine)-rhodium (I) chloride Smiles: C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.[Cl-].[Rh]; Information provided by Alfa Chemistry Materials. |
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