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Corning ULE® 7973 EUV Premium Grade Ultra Low Expansion Glass
Categories: Ceramic; Glass; Optical

Material Notes: 7973 is a titania-silicate low expansion glass that has been tailored to meet the needs for mask and optical substrates for EUVL applications. 7973 has a similar composition to ULE® 7972 glass and is made using the same flame deposition process. The lithography transition from 193nm to 13.4nm required a major design shift in stepper optics from refractive to reflective. In reflective optics, substrate materials should be purely passive. The incident light should reflect off of the multilayer coatings of the optics and the photomask without the introduction of any mechanical or optical distortion caused by the underlying substrate. To minimize distortion from the minute temperature changes and meet the stringent EUVL specifications, the substrates must have a near-zero coefficient of thermal expansion (CTE) and tightly controlled zero cross over range.

Excellent resistance to weathering. Exhibits virtually no surface clouding or electrical surface leakage when subjected to attack by water, sulfur dioxide, and other atmospheric gases. High resistance to attack by nearly all chemical agents.

ULE® 7973 comes in several grades with varying size/levels of inclusions and striae; CTE control, and birefringence. The distinguishing attributes of the EUV Premium Grade are low birefringence; low axial and radial CTE range; Tzc specified, low striae; low inclusions in the critical zone; and CTE Zero Cross Over Temperature User defined within 15°C to 32°C ± 5°C.

Information provided by Corning Incorporated.

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Physical PropertiesMetricEnglishComments
Density 2.21 g/cc0.0798 lb/in³
 
Mechanical PropertiesMetricEnglishComments
Hardness, Knoop 460460kg/mm² at 200g load
Tensile Strength, Ultimate 49.8 MPa7220 psi
Modulus of Elasticity 67.6 GPa9800 ksi
Bulk Modulus 34.1 GPa4950 ksi
Poissons Ratio 0.170.17
Shear Modulus 29.0 GPa4210 ksi
 
Electrical PropertiesMetricEnglishComments
Volume Resistivity 4.00e+11 ohm-cm
@Temperature 200 °C
4.00e+11 ohm-cm
@Temperature 392 °F
100Hz
 
Thermal PropertiesMetricEnglishComments
CTE, linear  -0.700 µm/m-°C
@Temperature -150 °C
-0.389 µin/in-°F
@Temperature -238 °F
Approximate Instantaneous Value
 -0.400 µm/m-°C
@Temperature -100 °C
-0.222 µin/in-°F
@Temperature -148 °F
Approximate Instantaneous Value
 -0.190 µm/m-°C
@Temperature -50.0 °C
-0.106 µin/in-°F
@Temperature -58.0 °F
Approximate Instantaneous Value
 -0.0300 µm/m-°C
@Temperature 3.00 °C
-0.0167 µin/in-°F
@Temperature 37.4 °F
Approximate Instantaneous Value
 -0.0300 - 0.0300 µm/m-°C
@Temperature 5.00 - 35.0 °C
-0.0167 - 0.0167 µin/in-°F
@Temperature 41.0 - 95.0 °F
Specified mean from 5 to 35°C
 0.0300 µm/m-°C
@Temperature 42.5 °C
0.0167 µin/in-°F
@Temperature 109 °F
Approximate Instantaneous Value
 0.0500 µm/m-°C
@Temperature 250 °C
0.0278 µin/in-°F
@Temperature 482 °F
Approximate Instantaneous Value
 0.0800 µm/m-°C
@Temperature 200 °C
0.0444 µin/in-°F
@Temperature 392 °F
Approximate Instantaneous Value
 0.0800 µm/m-°C
@Temperature 100 °C
0.0444 µin/in-°F
@Temperature 212 °F
Approximate Instantaneous Value
 0.0900 µm/m-°C
@Temperature 150 °C
0.0500 µin/in-°F
@Temperature 302 °F
Approximate Instantaneous Value
Specific Heat Capacity 0.767 J/g-°C0.183 BTU/lb-°F
Thermal Conductivity 1.31 W/m-K9.09 BTU-in/hr-ft²-°F
Softening Point 1490 °C2710 °F
Annealing Point 1000 °C1830 °F
Strain Point 890 °C1630 °F
 
Optical PropertiesMetricEnglishComments
Abbe Number 53.153.1vd
 
Descriptive Properties
Birefringence< 10 nm/cm
Stress Optical Coefficient4.15 (nm/cm)/(kg/cm²)
Striae100Non-Critical Zone. 0 to 400 Scale (%)
 50Critical Zone. 0 to 400 Scale (%)
Thermal Diffusivity.0079 cm²/s

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CCORNG972 / 233287

Specialty Compounds RTP Company

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